Step 1: Define endocrine vs exocrine.
Endocrine glands are ductless and secrete hormones into the bloodstream; exocrine glands secrete via ducts to surfaces.
Step 2: Classify the options.
Pituitary, thyroid, and adrenal are classic endocrine glands. The sweat gland is exocrine (ducts to skin), hence not endocrine.
Step 3: Conclude.
\[
\boxed{\text{Sweat gland (Option D).}}
\]