Step 1: Polymerisation behavior of formaldehyde.
Formaldehyde undergoes polymerisation reactions to form different products depending on the conditions.
Step 2: Identification of trimers.
Trioxane is the cyclic trimer of formaldehyde formed by acid-catalysed polymerisation and exists as a solid compound.
Step 3: Elimination of other options.
Metaldehyde and paraldehyde are polymers of acetaldehyde, while paraformaldehyde is a long-chain polymer of formaldehyde, not a trimer.
Step 4: Conclusion.
Hence, the solid trimer of formaldehyde is Trioxane.