Boiling point depends on the strength of intermolecular forces. The stronger the intermolecular forces, the higher the boiling point.
- \( \text{CH}_4 \) (methane) is a non-polar molecule with weak London dispersion forces, so it has a low boiling point.
- \( \text{H}_2O \) (water) has hydrogen bonding, a strong intermolecular force, giving it a relatively high boiling point.
- \( \text{NH}_3 \) (ammonia) also has hydrogen bonding, but it is weaker than that in water, so its boiling point is lower.
- \( \text{CO}_2 \) (carbon dioxide) is a non-polar molecule with weak London dispersion forces, resulting in a low boiling point.
Thus, \( \text{H}_2O \) has the highest boiling point due to its strong hydrogen bonding.