Assertion (A): The boiling point of ethanol is higher than that of methoxymethane. Reason (R): There is intramolecular hydrogen bonding in ethanol.
Assertion (A) is false, but Reason (R) is true.
Step 1: Understanding boiling point comparison. Ethanol has a higher boiling point than methoxymethane due to the presence of hydrogen bonding between ethanol molecules, which requires more energy to break these interactions.
Step 2: Reason for the boiling point difference. The intramolecular hydrogen bonding in ethanol is the reason for its higher boiling point compared to methoxymethane, as methoxymethane lacks such hydrogen bonding.
Step 3: Conclusion. Since both Assertion (A) and Reason (R) are true, and Reason (R) correctly explains Assertion (A), the correct answer is option (A). \vspace{10pt}
Reaction \( 2A \rightarrow B + 3C \) is a zero-order reaction. What will be the rate of production for "C"?
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.