Question:

Which of the following compounds give salt of an acid and alcohol on heating with concentrated KOH?

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Cannizzaro reaction occurs with aldehydes lacking alpha-hydrogens, like formaldehyde, yielding alcohol and acid salts.
Updated On: Jun 3, 2025
  • Formaldehyde
  • Acetaldehyde
  • Acetone
  • Acetophenone
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The Correct Option is A

Solution and Explanation

- When heated with concentrated KOH, formaldehyde undergoes the Cannizzaro reaction producing a salt of formic acid (acid) and methanol (alcohol).
- Acetaldehyde, acetone, and acetophenone do not undergo this reaction because acetaldehyde is capable of both oxidation and reduction but acetone and acetophenone are ketones and do not show Cannizzaro reaction.
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