Which of the following compound can give positive iodoform test when treated with aqueous KOH solution followed by potassium hypoiodite.
The Correct Option is B
Approach Solution - 1
The iodoform test is a chemical reaction used to identify the presence of methyl ketones (a ketone with a methyl group, \(-COCH_3\)) or specific alcohols that can be oxidized to methyl ketones. The reaction involves the compound being treated with aqueous potassium hydroxide (KOH) followed by potassium hypoiodite (KI/I2 solution).
To determine which compound among the given options can give a positive iodoform test, we need to check for the presence of the \(-COCH_3\) group or an alcohol that can be oxidized to it.
- Examine each compound:
- Compound 1: Does not have the \(-COCH_3\) group or an alcohol group that can be oxidized to give it.
- Compound 2: Contains a methyl ketone group (\(-COCH_3\)), which fits the criteria for the iodoform test.
- Compound 3: Does not have the \(-COCH_3\) group and cannot be oxidized to form one.
- Compound 4: Also lacks the \(-COCH_3\) group and cannot be easily oxidized to form one.
- Thus, Compound 2 is the only one that can give a positive iodoform test because it contains the necessary methyl ketone group.
Thus, the correct answer is Compound 2
Approach Solution -2
The correct answer is (2)
Top Questions on Solutions
- Consider the dissociation equilibrium of the following weak acid: \[ \mathrm{HA \rightleftharpoons H^+(aq) + A^-(aq)} \] If the \(pK_a\) of the acid is \(4\), then the pH of a \(10\ \text{mM}\) HA solution is ________ (Nearest integer). (Given: The degree of dissociation can be neglected with respect to unity)
- The crystal field splitting energy of $[Co(oxalate)_3]^3-$ complex is 'n' times that of the $[Cr(oxalate)_3]^3-$ complex. Here 'n' is_______ (Assume $\Delta_0 > P$)}
- The osmotic pressure of a living cell is 12 atm at 300 K. The strength of sodium chloride solution that is isotonic with the living cell at this temperature is ____________ g L$^{-1}$. (Nearest integer)
Given: R = 0.08 L atm K$^{-1}$ mol$^{-1}$
Assume complete dissociation of NaCl
(Given : Molar mass of Na and Cl are 23 and 35.5 g mol$^{-1}$ respectively.) A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.- At \(T\) K, \(100\,\text{g}\) of \(98%\) \(H_2SO_4\) (w/w) aqueous solution is mixed with \(100\,\text{g}\) of \(49%\) \(H_2SO_4\) (w/w) aqueous solution. What is the mole fraction of \(H_2SO_4\) in the resultant solution? (Given: Atomic mass \(H = 1\,u,\; S = 32\,u,\; O = 16\,u\). Assume that temperature after mixing remains constant.)
Questions Asked in JEE Main exam
Let \( \alpha = \dfrac{-1 + i\sqrt{3}}{2} \) and \( \beta = \dfrac{-1 - i\sqrt{3}}{2} \), where \( i = \sqrt{-1} \). If
\[ (7 - 7\alpha + 9\beta)^{20} + (9 + 7\alpha - 7\beta)^{20} + (-7 + 9\alpha + 7\beta)^{20} + (14 + 7\alpha + 7\beta)^{20} = m^{10}, \] then the value of \( m \) is ___________.- JEE Main - 2026
- Complex Numbers and Quadratic Equations
- The work functions of two metals ($M_A$ and $M_B$) are in the 1 : 2 ratio. When these metals are exposed to photons of energy 6 eV, the kinetic energy of liberated electrons of $M_A$ : $M_B$ is in the ratio of 2.642 : 1. The work functions (in eV) of $M_A$ and $M_B$ are respectively.
- JEE Main - 2026
- Dual nature of matter
- 10 mole of an ideal gas is undergoing the process shown in the figure. The heat involved in the process from \( P_1 \) to \( P_2 \) is \( \alpha \) Joule \((P_1 = 21.7 \text{ Pa}, P_2 = 30 \text{ Pa}, C_v = 21 \text{ J/K mol}, R = 8.3 \text{ J/mol K})\). The value of \( \alpha \) is ________.
- JEE Main - 2026
- Thermodynamics
- The system of linear equations
$x + y + z = 6$
$2x + 5y + az = 36$
$x + 2y + 3z = b$
has- JEE Main - 2026
- Matrices and Determinants
- The displacement of a particle executing simple harmonic motion with time period \(T\) is expressed as \[ x(t)=A\sin\omega t, \] where \(A\) is the amplitude of oscillation. If the maximum value of the potential energy of the oscillator is found at \[ t=\frac{T}{2\beta}, \] then the value of \(\beta\) is ________.
- JEE Main - 2026
- Waves and Oscillations