Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of the above statements, choose the correct answer from the options given below:
Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. $(\mathrm{B}<\mathrm{Al}),(\mathrm{Al}<\mathrm{Ga}),(\mathrm{Ga}<\mathrm{In})$ and $(\mathrm{In}<\mathrm{Tl})$ Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius $\left(\mathrm{M}^{3+}\right)$ than the other one. The atomic number of the element (X) is
Given below are two statements. 
In the light of the above statements, choose the correct answer from the options given below:
200 ml of an aqueous solution contains 3.6 g of Glucose and 1.2 g of Urea maintained at a temperature equal to 27$^{\circ}$C. What is the Osmotic pressure of the solution in atmosphere units?
Given Data R = 0.082 L atm K$^{-1}$ mol$^{-1}$
Molecular Formula: Glucose = C$_6$H$_{12}$O$_6$, Urea = NH$_2$CONH$_2$