All of the above
Step 1: Understanding Infrared (IR) Spectroscopy. - Infrared spectroscopy is used to study molecular vibrations by detecting changes in dipole moment. - IR radiation excites vibrational modes like stretching and bending, causing variations in molecular dipole moment.
Step 2: Explanation of molecular movement. - Dipole movement: Required for IR activity since molecules must undergo a change in dipole moment when vibrating. - Spin movement: Relevant in NMR spectroscopy, not IR spectroscopy. - Round movement: Not a recognized molecular motion in spectroscopy.
Step 3: Explanation of incorrect options. - (B) Spin movement: Incorrect, as spin transitions are detected in NMR spectroscopy, not IR. - (C) Round movement: Incorrect, as no such term exists in molecular spectroscopy. - (D) All of the above: Incorrect, since only dipole movement is essential for IR spectroscopy.
Step 4: Selecting the correct option. Since IR spectroscopy requires a change in dipole moment, the correct answer is (A) Dipole movement.
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is:
The 1H NMR spectrum of the given iridium complex at room temperature gave a single signal at 2.6 ppm, and its 31P NMR spectrum gave a single signal at 23.0 ppm. When the spectra were recorded at lower temperatures, both these signals split into a complex pattern. The intra-molecular dynamic processes shown by this molecule are:
A closed-loop system has the characteristic equation given by: $ s^3 + k s^2 + (k+2) s + 3 = 0 $.
For the system to be stable, the value of $ k $ is:
A digital filter with impulse response $ h[n] = 2^n u[n] $ will have a transfer function with a region of convergence.