Step 1: Understand P-type semiconductors.
P-type semiconductors are formed when a trivalent (Group 13) impurity is added to a tetravalent semiconductor like silicon. This creates holes as the majority charge carriers. Step 2: Analyze the given options. (A) Sb: Antimony is pentavalent and forms N-type semiconductor. (B) Bi: Bismuth is also pentavalent and forms N-type semiconductor. (C) B: Boron is trivalent and creates holes, hence forms P-type semiconductor. (D) As: Arsenic is pentavalent and forms N-type semiconductor. Step 3: Conclusion.
Boron forms P-type semiconductor when added to silicon.