Step 1: Understanding the composition of vinegar
Vinegar is a liquid that results from the fermentation of ethanol. This process is carried out by bacteria known as \textit{Acetobacter}, which oxidize ethanol into acetic acid.
Thus, the main acidic component of vinegar is acetic acid.
Step 2: Chemical formula of acetic acid
The chemical formula of acetic acid is:
$$
\text{CH}_3\text{COOH}
$$
This weak acid gives vinegar its distinct sour taste and sharp odor.
Step 3: Analyzing the other options
Let’s examine why the other choices are incorrect:
Formic acid ($ \text{HCOOH} $): Found in ant secretions and some insect bites, not in vinegar.
Citric acid: Present in citrus fruits like lemons and oranges, not in vinegar.
Malic acid: Found in apples and other fruits, also not a primary constituent of vinegar.
None of these acids are produced during the fermentation of ethanol to form vinegar.
Step 4: Conclusion
Since acetic acid is the principal organic acid in vinegar, the correct answer is:
(2) Acetic acid