Question:

When an excess and a very dilute aqueous solution of $ KI $ is added to a very dilute aqueous solution of silver nitrate, the colloidal particles of silver iodide are associated with the Helmholtz double layer

Updated On: Jun 2, 2024
  • $ AgI : Ag^{+} : NO_{3}^{-} $
  • $ AgI: K^{+} : NO_{3}^{-} $
  • $ AgI : NO_{3}^{-} : Ag^{+} $
  • $ AgI : I^{-} : K^{+} $
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The Correct Option is D

Solution and Explanation

The Helmholtz double layer contains a layer of opposite charges on the surface of colloidal particles.
$ AgNO_{3}+\underset{\text{excess}}{KI}\,\rightarrow AgI+KNO_{3} $
$ AgI+KI\rightarrow AgI : I^{-} : K^{+} $
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Concepts Used:

Surface Chemistry

The study of the chemical phenomena that occur at the interface of two surfaces which can be solid-liquid, solid-gas, solid-vacuum, liquid-gas, etc. 

Read Also: Surface Chemistry

Applications of surface chemistry are:

Adsorption:

The process of attraction and aggregation of the molecules of a substance on the surface of a solid is known as adsorption. For Example, N2 adsorbs on the surface of activated charcoal

Two types of adsorption are:-

  • Chemisorption: It is also known as Chemical Adsorption.
  • Physisorption: It is also known as Physical Adsorption.

Corrosion:

The process through which the refined metals convert themselves into more stable compounds is known as corrosion.

Crystallisation:

The type of technique used in order to purify the substances to separate Solids from liquids is known as crystallisation.

Heterogeneous Catalysis:

The process wherein a catalyst is used in order to increase the rate of a chemical reaction is known as catalysis. The catalyst does not undergo any transformation and can be recovered in a chemically unchanged state. 

There are two types of catalysis:-

  • When the catalyst involved and the reacting substances are same states of matter or in the same phase, it is known as Homogeneous Catalysis.
  • When the catalyst involved and the reacting substances are in different states of matter or different phases, it is known as Heterogeneous Catalysis.