Question:

When a monosaccharide forms a cyclic hemiacetal, the carbon atom that contained the carbonyl group is identified as the … carbon atom, because

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In monosaccharides, the anomeric carbon is the one that was part of the carbonyl group and forms the cyclic structure.
Updated On: Jan 6, 2026
  • The carbonyl group is drawn to the right
  • The carbonyl group is drawn to the left
  • Acetal forms bond to an -OR and an —OH
  • Anomeric, its substituents can assume an \( \alpha \) or \( \beta \) position
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The Correct Option is D

Solution and Explanation


Step 1: Understanding hemiacetal formation.
When a monosaccharide forms a cyclic hemiacetal, the carbon atom that was part of the carbonyl group becomes the anomeric carbon. This carbon can assume either an \( \alpha \)- or \( \beta \)-anomeric form.

Step 2: Conclusion.
The correct identification is that the anomeric carbon can assume either an \( \alpha \)- or \( \beta \)-position, corresponding to option (4).
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