Prime sums possible from two dice are 2, 3, 5, 7, and 11. We identify the outcomes where the sum is prime and calculate the scenarios where at least one number is a multiple of 3:
\[
\text{Prime sums pairs:} (2,3,5,7,11)
\]
\[
\text{Total prime outcomes:} 15
\]
\[
\text{Multiple of 3 in outcomes:} (1,2), (2,1), (3,2), (2,3), (4,3), (3,4)
\]
\[
\text{Favorable outcomes:} 8
\]
\[
P(\text{Multiple of 3} \mid \text{Prime Sum}) = \frac{8}{15}
\]