Step 1: Understanding pyrolusite ore.
Pyrolusite is an important manganese ore, and its formula is \( \text{MnO}_2 \). It consists mainly of manganese dioxide.
Step 2: Analyzing the options.
(A) PbCrO₄: Incorrect, this is the formula of chrome yellow.
(B) Cu₂O: Incorrect, this is the formula of copper(I) oxide.
(C) Cr₂O₃: Incorrect, this is the formula of chromium(III) oxide.
(D) MnO₂: Correct — This is the formula of pyrolusite ore.
Step 3: Conclusion.
The correct answer is (D) MnO₂.