Question:

What happens when C₆H₅–O–R is treated with HX?

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When an ether (C₆H₅–O–R) reacts with HX, it undergoes cleavage at the oxygen atom, forming a phenol and an alkyl halide.
Updated On: Sep 9, 2025
  • RX and C₆H₅OH are formed
  • ROH and C₆H₅X are formed
  • C₆H₄X₂ and ROH are formed
  • RX and C₆H₅X are formed
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The Correct Option is B

Solution and Explanation

In the reaction between C₆H₅–O–R and HX, the phenolic group (C₆H₅OH) is formed along with the alkyl halide (C₆H₅X). This is an example of nucleophilic substitution where the alkyl group (R) is substituted by the halide ion (X).
Step 1: Evaluate the reaction.
The O-R bond breaks, and the phenol (C₆H₅OH) is formed along with the alkyl halide (C₆H₅X).
Step 2: Conclusion.
Thus, the correct answer is that ROH and C₆H₅X are formed.
Final Answer: \[ \boxed{\text{ROH and C₆H₅X are formed.}} \]
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