What does the Third Law of Thermodynamics state about the entropy of a perfect crystal at absolute zero temperature?
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Third Law of Thermodynamics. The entropy (S) of a perfect crystal approaches zero as the absolute temperature (T) approaches zero Kelvin. \( \lim_{T\to 0 S = 0 \).
The Third Law of Thermodynamics deals with the behavior of entropy as the temperature approaches absolute zero (0 Kelvin). It states that the entropy of a perfect crystalline substance approaches zero as the absolute temperature approaches zero. A perfect crystal at absolute zero represents the state of minimum energy and maximum order (only one possible microstate), corresponding to zero entropy (S=0). While reaching absolute zero is practically impossible, the law states that entropy tends towards zero as T \(\rightarrow\) 0 K.