Given that the two spheres have the same surface charge density \( \sigma \), we know the total charge on each sphere is given by:
\[
Q = \sigma \times \text{Surface area}
\]
For the smaller sphere, with radius \( R \), the surface area is \( 4 \pi R^2 \).
Hence, the total charge on the smaller sphere is:
\[
Q_{\text{small}} = \sigma \times 4 \pi R^2
\]
For the larger sphere, with radius \( 3R \), the surface area is \( 4 \pi (3R)^2 = 36 \pi R^2 \).
Hence, the total charge on the larger sphere is:
\[
Q_{\text{large}} = \sigma \times 36 \pi R^2
\]
When the spheres are brought into contact, charge will flow between them until they reach the same potential.
Since the potential of a sphere is given by \( V = \frac{Q}{4 \pi \epsilon_0 r} \), the potentials of the two spheres must be equal when they are in contact.
Let the charge on the smaller sphere after contact be \( Q_1 \) and on the larger sphere be \( Q_2 \).
Using the condition for equal potentials:
\[
\frac{Q_1}{4 \pi \epsilon_0 R} = \frac{Q_2}{4 \pi \epsilon_0 (3R)}
\]
Simplifying:
\[
Q_1 = \frac{Q_2}{3}
\]
Since charge is conserved:
\[
Q_1 + Q_2 = Q_{\text{small}} + Q_{\text{large}} = \sigma \times 4 \pi R^2 + \sigma \times 36 \pi R^2 = 40 \pi R^2 \sigma
\]
Substituting \( Q_1 = \frac{Q_2}{3} \) into this:
\[
\frac{Q_2}{3} + Q_2 = 40 \pi R^2 \sigma
\]
Solving for \( Q_2 \):
\[
\frac{4 Q_2}{3} = 40 \pi R^2 \sigma \quad \Rightarrow \quad Q_2 = 30 \pi R^2 \sigma
\]
Now, using \( Q_2 = 30 \pi R^2 \sigma \) to find the surface charge density on the larger sphere after separation:
\[
\sigma_2 = \frac{Q_2}{36 \pi R^2} = \frac{30 \pi R^2 \sigma}{36 \pi R^2} = \frac{5 \sigma}{6}
\]
For the smaller sphere:
\[
\sigma_1 = \frac{Q_1}{4 \pi R^2} = \frac{10 \pi R^2 \sigma}{4 \pi R^2} = \frac{5 \sigma}{2}
\]
Finally, the ratio \( \frac{\sigma_1}{\sigma_2} \) is:
\[
\frac{\sigma_1}{\sigma_2} = \frac{\frac{5 \sigma}{2}}{\frac{5 \sigma}{6}} = 3
\]
Thus, the correct answer is Option 4.