Three point charges \( +q, +2q, \) and \( +4q \) are placed along a straight line such that the charge \( +2q \) lies equidistant from the other two charges. The ratio of the net electrostatic force on charges \( +q \) and \( +4q \) is:
Let the charges \( +q \) and \( +4q \) be at positions \( x = -a \) and \( x = +a \) respectively, with \( +2q \) at the origin. The forces due to each charge on the other are given by Coulomb's law: \[ F = k \frac{|q_1q_2|}{r^2} \] where \( k \) is Coulomb's constant.
Force on \( +q \): The force on \( +q \) due to \( +2q \) is: \[ F_{q \to 2q} = k \frac{|q \cdot 2q|}{a^2} = k \frac{2q^2}{a^2} \] Similarly, the force on \( +q \) due to \( +4q \) is: \[ F_{q \to 4q} = k \frac{|q \cdot 4q|}{(2a)^2} = k \frac{4q^2}{4a^2} = k \frac{q^2}{a^2} \] Thus, the net force on \( +q \) is: \[ F_{{net}, q} = F_{q \to 2q} + F_{q \to 4q} = k \frac{2q^2}{a^2} + k \frac{q^2}{a^2} = k \frac{3q^2}{a^2} \]
Force on \( +4q \): The force on \( +4q \) due to \( +2q \) is: \[ F_{4q \to 2q} = k \frac{|4q \cdot 2q|}{a^2} = k \frac{8q^2}{a^2} \] Similarly, the force on \( +4q \) due to \( +q \) is: \[ F_{4q \to q} = k \frac{|4q \cdot q|}{(2a)^2} = k \frac{4q^2}{4a^2} = k \frac{q^2}{a^2} \] Thus, the net force on \( +4q \) is: \[ F_{{net}, 4q} = F_{4q \to 2q} + F_{4q \to q} = k \frac{8q^2}{a^2} + k \frac{q^2}{a^2} = k \frac{9q^2}{a^2} \]
Ratio of Forces: The ratio of the net forces on \( +q \) and \( +4q \) is: \[ {Ratio} = \frac{F_{{net}, q}}{F_{{net}, 4q}} = \frac{k \frac{3q^2}{a^2}}{k \frac{9q^2}{a^2}} = \frac{3}{9} = \frac{1}{3} \] Thus, the ratio of the net electrostatic forces is \( 1 : 3 \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))