Step 1: Using the photoelectric equation.
The maximum kinetic energy of the emitted electron is given by:
\[
K.E. = h\nu - \phi
\]
Where \( h\nu \) is the energy of the photon and \( \phi \) is the work function of the metal.
Step 2: Kinetic energy for each case.
For the first case with photon energy 2.5 eV:
\[
K.E_1 = 2.5 \, \text{eV} - 2.0 \, \text{eV} = 0.5 \, \text{eV}
\]
For the second case with photon energy 4.5 eV:
\[
K.E_2 = 4.5 \, \text{eV} - 2.0 \, \text{eV} = 2.5 \, \text{eV}
\]
Step 3: Maximum speed of emitted electrons.
The kinetic energy of the electron is related to its speed by:
\[
K.E. = \frac{1}{2} m v^2
\]
Where \( m \) is the mass of the electron and \( v \) is its speed. Thus, the ratio of the maximum speeds is:
\[
\frac{v_2}{v_1} = \sqrt{\frac{K.E_2}{K.E_1}} = \sqrt{\frac{2.5}{0.5}} = \sqrt{5} \approx 2.24
\]
Thus, the ratio of the maximum speeds of the electrons is approximately 2.24.