For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively:
\[ f(x) = \begin{cases} x\left( \frac{\pi}{2} + x \right), & \text{if } x \geq 0 \\ x\left( \frac{\pi}{2} - x \right), & \text{if } x < 0 \end{cases} \]
Then \( f'(-4) \) is equal to:If \( f'(x) = 4x\cos^2(x) \sin\left(\frac{x}{4}\right) \), then \( \lim_{x \to 0} \frac{f(\pi + x) - f(\pi)}{x} \) is equal to:
Let \( f(x) = \frac{x^2 + 40}{7x} \), \( x \neq 0 \), \( x \in [4,5] \). The value of \( c \) in \( [4,5] \) at which \( f'(c) = -\frac{1}{7} \) is equal to:
The rate of a chemical reaction is defined as the change in concentration of any one of the reactants or products per unit time.
Consider the reaction A → B,
Rate of the reaction is given by,
Rate = −d[A]/ dt=+d[B]/ dt
Where, [A] → concentration of reactant A
[B] → concentration of product B
(-) A negative sign indicates a decrease in the concentration of A with time.
(+) A positive sign indicates an increase in the concentration of B with time.
There are certain factors that determine the rate of a reaction: