The van�t Hoff factor $i$ for an electrolyte which undergoes dissociation and association in solvents are respectively
- greater than 1 and greater than 1
- less than 1 and greater than 1
- less than 1 and less than 1
- greater than 1 and less than 1
The Correct Option is D
Solution and Explanation
Top Questions on Colligative Properties
- Arrange the following solutions in order of their increasing boiling points.
(i) \(10^{-4}\) M NaCl
(ii) \(10^{-4}\) M Urea
(iii) \(10^{-3}\) M NaCl
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- CrCl\(_3\).xNH\(_3\) can exist as a complex. 0.1 molal aqueous solution of this complex shows a depression in freezing point of 0.558°C. Assuming 100\% ionization of this complex and coordination number of Cr is 6, the complex will be:
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- Consider the given plots of vapor pressure (VP) vs temperature (T/K). Which amongst the following options is the correct graphical representation showing \( \Delta T_f \) depression in the freezing point of solvent in a solution?
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A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
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(A) Give reasons: (a) Cooking is faster in a pressure cooker than in an open pan. (b) On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult's law is shown by the resulting solution? What change in temperature would you observe after mixing liquids X and Y?
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Concepts Used:
Colligative Properties
Colligative Property of any substance is entirely dependent on the ratio of the number of solute particles to the total number of solvent particles but does not depend on the nature of particles. There are four colligative properties: vapor pressure lowering, boiling point elevation, freezing point depression, and osmotic pressure.
Examples of Colligative Properties
We can notice the colligative properties of arrangements by going through the accompanying examples:
- On the off chance that we add a spot of salt to a glass full of water, its freezing temperature is brought down impressively than its normal temperature. On the other hand, the boiling temperature is likewise increased and the arrangement will have a lower vapor pressure. There are also changes observed in its osmotic pressure.
- In the same way, if we add alcohol to water, the solution’s freezing point goes down below the normal temperature that is usually observed for either pure alcohol or water.
Types of Colligative Properties
- Freezing point depression: ΔTf =1000 x kf x m2 /(M2 x m1)
- Boiling point elevation: ΔTb = kb m
- Osmotic pressure: π = (n2/V) RT
- Relative lowering of vapor pressure: (Po - Ps)/Po