Let the complex number be \( z = \frac{2 - \alpha i}{\alpha - i} \).
To determine the value of \( \alpha \) such that \( z \) is purely imaginary, we must eliminate the real part of the complex number.
First, multiply both the numerator and denominator by the complex conjugate of the denominator \( \alpha + i \):
\[
z = \frac{(2 - \alpha i)(\alpha + i)}{(\alpha - i)(\alpha + i)}.
\]
The denominator simplifies using the difference of squares:
\[
(\alpha - i)(\alpha + i) = \alpha^2 + 1.
\]
Now, expand the numerator:
\[
(2 - \alpha i)(\alpha + i) = 2\alpha + 2i - \alpha^2 i - \alpha i^2.
\]
Since \( i^2 = -1 \), this becomes:
\[
2\alpha + 2i - \alpha^2 i + \alpha.
\]
Now group the real and imaginary parts:
\[
{Real part: } 2\alpha + \alpha = 3\alpha, \quad {Imaginary part: } 2 - \alpha^2.
\]
Thus, we have:
\[
z = \frac{3\alpha + (2 - \alpha^2)i}{\alpha^2 + 1}.
\]
For \( z \) to be purely imaginary, the real part must be 0:
\[
3\alpha = 0 \quad \Rightarrow \quad \alpha = 0.
\]
Thus, the value of \( \alpha \) for which \( z \) is purely imaginary is \( \alpha = 0 \).