Step 1: Using the cosine rule.
We are given the sides of the triangle as:
\[
a = \sin\alpha, \quad b = \cos\alpha, \quad c = \sqrt{1 + \sin\alpha \cos\alpha}.
\]
To find the greatest angle, we use the cosine rule:
\[
\cos C = \frac{a^2 + b^2 - c^2}{2ab}.
\]
Substituting the values of \(a\), \(b\), and \(c\), we get:
\[
\cos C = \frac{\sin^2\alpha + \cos^2\alpha - (1 + \sin\alpha \cos\alpha)}{2\sin\alpha \cos\alpha}.
\]
Using the identity \(\sin^2\alpha + \cos^2\alpha = 1\), this simplifies to:
\[
\cos C = \frac{1 - (1 + \sin\alpha \cos\alpha)}{2\sin\alpha \cos\alpha} = \frac{-\sin\alpha \cos\alpha}{2\sin\alpha \cos\alpha} = -\frac{1}{2}.
\]
Therefore, \(C = 120^\circ\).