Given,
Conductivity, \(k\) = 0.146 × 10-3 S cm-1
Resistance, R = 1500 Ω
Cell constant = \(k\) × R
= 0.146 × 10-3 × 1500
= 0.219 cm -1
The molar conductance of an infinitely dilute solution of ammonium chloride was found to be 185 S cm$^{-1}$ mol$^{-1}$ and the ionic conductance of hydroxyl and chloride ions are 170 and 70 S cm$^{-1}$ mol$^{-1}$, respectively. If molar conductance of 0.02 M solution of ammonium hydroxide is 85.5 S cm$^{-1}$ mol$^{-1}$, its degree of dissociation is given by x $\times$ 10$^{-1}$. The value of x is ______. (Nearest integer)
Consider the following half cell reaction $ \text{Cr}_2\text{O}_7^{2-} (\text{aq}) + 6\text{e}^- + 14\text{H}^+ (\text{aq}) \longrightarrow 2\text{Cr}^{3+} (\text{aq}) + 7\text{H}_2\text{O}(1) $
The reaction was conducted with the ratio of $\frac{[\text{Cr}^{3+}]^2}{[\text{Cr}_2\text{O}_7^{2-}]} = 10^{-6}$
The pH value at which the EMF of the half cell will become zero is ____ (nearest integer value)
[Given : standard half cell reduction potential $\text{E}^\circ_{\text{Cr}_2\text{O}_7^{2-}, \text{H}^+/\text{Cr}^{3+}} = 1.33\text{V}, \quad \frac{2.303\text{RT}}{\text{F}} = 0.059\text{V}$
| Concentration of KCl solution (mol/L) | Conductivity at 298.15 K (S cm-1) | Molar Conductivity at 298.15 K (S cm2 mol-1) |
|---|---|---|
| 1.000 | 0.1113 | 111.3 |
| 0.100 | 0.0129 | 129.0 |
| 0.010 | 0.00141 | 141.0 |
Conductance is an expression of the ease with which electric current flows through materials like metals and nonmetals. In equations, an uppercase letter G symbolizes conductance. The standard unit of conductance is siemens (S), formerly known as mho.
Conductance in electricity is considered the opposite of resistance (R). Resistance is essentially the amount of friction a component presents to the flow of current.