Choose the option that correctly matches the items in Group 1 with those in Group 2.

Step 1: Define Each Phenomenon.
Coking involves the deposition of carbon materials, which fits with (II).
Poisoning is caused by the irreversible binding of molecules, fitting with (III).
Sintering occurs due to prolonged high temperatures, fitting with (I).
Step 2: Match to the Descriptions.
The matches have been verified based on standard definitions and typical catalyst behavior in industrial processes.
Methanol is produced by the reversible, gas-phase hydrogenation of carbon monoxide: \[ {CO} + 2{H}_2 \rightleftharpoons {CH}_3{OH} \] CO and H$_2$ are charged to a reactor, and the reaction proceeds to equilibrium at 453 K and 2 atm. The reaction equilibrium constant, which depends only on the temperature, is 1.68 at the reaction conditions. The mole fraction of H$_2$ in the product is 0.4. Assuming ideal gas behavior, the mole fraction of methanol in the product is ____________ (rounded off to 2 decimal places).
Which element of the 3d series has the lowest enthalpy of atomisation and why?
The residence-time distribution (RTD) function of a reactor (in min−1) is:
\[ E(t) = \begin{cases} 1 - 2t, & \text{if } t \leq 0.5\ \text{min} \\ 0, & \text{if } t > 0.5\ \text{min} \end{cases} \]
The mean residence time of the reactor is _____ min (rounded off to 2 decimal places).
Oil is extracted from mustard seeds having 20 wt% oil and 80 wt% solids, using hexane as a solvent. After extraction, the hexane-free residual cake contains 1 wt% oil. Assuming negligible dissolution of cake in hexane, the percentage oil recovery in hexane is ___________ % (rounded off to the nearest integer).
An electrical wire of 2 mm diameter and 5 m length is insulated with a plastic layer of thickness 2 mm and thermal conductivity \( k = 0.1 \) W/(m·K). It is exposed to ambient air at 30°C. For a current of 5 A, the potential drop across the wire is 2 V. The air-side heat transfer coefficient is 20 W/(m²·K). Neglecting the thermal resistance of the wire, the steady-state temperature at the wire-insulation interface __________°C (rounded off to 1 decimal place).

GIVEN:
Kinematic viscosity: \( \nu = 1.0 \times 10^{-6} \, {m}^2/{s} \)
Prandtl number: \( {Pr} = 7.01 \)
Velocity boundary layer thickness: \[ \delta_H = \frac{4.91 x}{\sqrt{x \nu}} \]
The first-order irreversible liquid phase reaction \(A \to B\) occurs inside a constant volume \(V\) isothermal CSTR with the initial steady-state conditions shown in the figure. The gain, in kmol/m³·h, of the transfer function relating the reactor effluent \(A\) concentration \(c_A\) to the inlet flow rate \(F\) is:

A hot plate is placed in contact with a cold plate of a different thermal conductivity as shown in the figure. The initial temperature (at time $t = 0$) of the hot plate and cold plate are $T_h$ and $T_c$, respectively. Assume perfect contact between the plates. Which one of the following is an appropriate boundary condition at the surface $S$ for solving the unsteady state, one-dimensional heat conduction equations for the hot plate and cold plate for $t>0$?

The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:

\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is _________ MPa (rounded off to 3 decimal places).