Question:

The reaction stated below is named as

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Kolbe’s reaction involves the decarboxylation of carboxylates to form carboxylic acids in the presence of sodium hydroxide and carbon dioxide.
Updated On: Feb 4, 2026
  • Kolbe's reaction
  • Sandmeyer's reaction
  • Reimer-Tiemann reaction
  • Stephen reaction
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The Correct Option is A

Solution and Explanation

Step 1: Understanding Kolbe's reaction.
Kolbe’s reaction is a decarboxylation reaction of carboxylates in the presence of a strong base, followed by the addition of carbon dioxide. The reaction given in the question represents the Kolbe reaction, which leads to the formation of a carboxylic acid.
Step 2: Analyzing the options.
(A) Kolbe's reaction: Correct — This is the correct reaction, where sodium phenoxide reacts with carbon dioxide to form salicylic acid.
(B) Sandmeyer's reaction: Incorrect. This involves the conversion of diazonium salts to aryl halides, not a decarboxylation.
(C) Reimer-Tiemann reaction: Incorrect. This reaction involves the introduction of a formyl group to a phenol molecule.
(D) Stephen reaction: Incorrect. This reaction is related to the formation of imines, not a decarboxylation.
Step 3: Conclusion.
The correct answer is (A) Kolbe's reaction, which is a decarboxylation reaction that leads to the formation of a carboxylic acid.
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