Comprehension

The reaction of K3[Fe(CN)6] with freshly prepared FeSO4 solution produces a dark blue precipitate called Turnbull’s blue. The reaction of K4[Fe(CN)6] with the FeSO4 solution in the complete absence of air produces a white precipitate X, which turns blue in the air. Mixing the FeSO4 solution with NaNO3, followed by slow addition of concentrated H2SO4 through the side of the test tube produces a brown ring.

Question: 1

Precipitate X is

Updated On: May 24, 2024
  • Fe4[Fe(CN)6]3

  • Fe4[Fe(CN)6]

  • K2Fe[Fe(CN)6]

  • KFe[Fe(CN)6]

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The Correct Option is C

Solution and Explanation

The correct answer is K2Fe[Fe(CN)6]

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Question: 2

Among the following, the brown ring is due to the formation of

Updated On: May 23, 2024
  • \([Fe(NO)_2(SO_4)_2]^{2-}\)

  • \([Fe(NO)_2(H_2O)_4]^{3+}\)

  • \([Fe(NO)_4(SO_4)_2]\)

  • \([Fe(NO)(H_2O)_5]^{2+}\)

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The Correct Option is D

Solution and Explanation

The correct answer is \([Fe(NO)(H_2O)_5]^{2+}\) option (D)

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