Step 1: Understanding Sandmeyer Reaction
The Sandmeyer reaction is used to substitute diazonium groups with halogens, facilitated by CuCl or CuBr.
Reaction Mechanism
\[
C_6H_5N_2^+Cl^- + CuCl \longrightarrow C_6H_5Cl + N_2
\]
This reaction replaces the diazonium group with chlorine, forming chlorobenzene.
Conclusion
Thus, the correct answer is:
\[
\text{Sandmeyer reaction}
\]