Step 1: Recall nutrient mobility in plants.
- Some nutrients are mobile in plants, meaning they can move both upwards (acropetal) and downwards (basipetal).
- Some nutrients are immobile and move only acropetally through xylem.
Step 2: Behavior of Calcium.
- Calcium is absorbed from the soil and transported only upward (acropetal movement) in the xylem.
- It is not retranslocated from older to younger tissues, making it immobile in phloem.
- Hence, deficiency symptoms appear first in young tissues.
Step 3: Eliminate other options.
- Nitrogen: Mobile, moves through xylem and phloem.
- Sulphur: Semi-mobile, but not strictly acropetal.
- Potassium: Highly mobile nutrient.
Step 4: Conclusion.
The nutrient with acropetal-only movement in xylem is Calcium.
Final Answer: \[ \boxed{\text{Calcium moves only acropetally in plants.}} \]