Question:

The number of molecules having one lone pair of electrons on the central atom is from the following list: SnCl2_2, XeF6_6, SO3_3, ClF3_3, BrF5_5, H2_2O, XeO3_3. 

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To determine the number of lone pairs on the central atom, consider the electron domain geometry and the molecular geometry, where lone pairs affect the molecular shape.
Updated On: Mar 25, 2025
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The Correct Option is C

Solution and Explanation

Examining each molecule for the presence of a lone pair on the central atom:
- SnCl2_2: Bent geometry with one lone pair on Sn.
- XeF6_6: Distorted octahedral geometry with one lone pair on Xe.
- SO3_3: Trigonal planar with no lone pairs on S.
- ClF3_3: T-shaped with one lone pair on Cl.
- BrF5_5: Square pyramidal with one lone pair on Br.
- H2_2O: Bent geometry with two lone pairs on O.
- XeO3_3: Pyramidal with one lone pair on Xe.
Molecules with exactly one lone pair on the central atom are SnCl2_2, XeF6_6, ClF3_3, BrF5_5, and XeO3_3, totaling five.
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