Question:

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and  choose the correct option. 

 

Updated On: June 02, 2025
  • P →2; Q→4 ; R →1; S →3

  • P →1; Q→3 ; R →5; S →2

  • P →3; Q→2 ; R →1; S →4

  • P →3; Q→4 ; R →5; S →2

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The Correct Option is D

Approach Solution - 1

To solve the problem, we'll analyze the named reactions in List-I and identify the corresponding major products from List-II. Let's match each:

1. Aldol CondensationA reaction involving the formation of β-hydroxy ketone (aldol) followed by dehydration resulting in α,β-unsaturated ketone. In List-II, this product is associated with compound 4.
2. Finkelstein ReactionA halogen exchange reaction used to convert alkyl chlorides/bromides to iodides using sodium iodide, corresponding to compound 5 in List-II.
3. Sandmeyer ReactionA substitution reaction that converts diazonium salts to aryl halides, often involving the replacement of a diazo group with a halide ion. The right match here is compound 2 from List-II. 
4. Williamson Ether SynthesisA reaction for the synthesis of ethers from alkoxides and alkyl halides, matching with compound 3 in List-II.

Based on these connections, we get:

  • P (Aldol Condensation) → 3
  • Q (Finkelstein Reaction) → 4
  • R (Sandmeyer Reaction) → 5
  • S (Williamson Ether Synthesis) → 2

Thus, the correct option is: P →3; Q→4 ; R →5; S →2

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Approach Solution -2

Correct option is (D) P → 3; Q → 4; R → 5; S → 2 (P) → (3) 

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Concepts Used:

Organic Chemistry - Some Basic Principles and Techniques

Organic Chemistry is a subset of chemistry dealing with compounds of carbon. Therefore, we can say that Organic chemistry is the chemistry of carbon compounds and is 200-225 years old. Carbon forms bond with itself to form long chains of hydrocarbons, e.g.CH4, methane and CH3-CH3 ethane. Carbon has the ability to form carbon-carbon bonds quite elaborately. Polymers like polyethylene is a linear chain where hundreds of CH2 are linked together. 

Read Also: Organic Compounds

Importance of Organic Chemistry:

Organic chemistry is applicable in a variety of areas including-

  • Medicines: Example- Aspirin which is a headache medicine and Ibuprofen is a painkiller, both are organic compounds. Other examples include paracetamol.
  • Food: Example- Starch which is a carbohydrate is an organic compound and a constituent of rice and other grains. It is the source of energy.
  • Clothing: Example- Nylon, Polyester and Cotton are forms of organic compounds.
  • Fuels: Examples- Gasoline, Petrol and Diesel are organic compounds used in the automobile industry at large.