Step 1: Find slope of the line joining the points:
\[
m = \frac{-2 - 3}{5 - 0} = \frac{-5}{5} = -1
\]
The curve is:
\[
y = \frac{C}{x + 1}
\Rightarrow \text{Differentiate: } \frac{dy}{dx} = -\frac{C}{(x + 1)^2}
\]
Let the point of tangency be \( (x_0, y_0) \) on the curve.
We are told the line with slope -1 is tangent to the curve, so:
\[
-\frac{C}{(x_0 + 1)^2} = -1 \Rightarrow C = (x_0 + 1)^2 \quad \text{(1)}
\]
Also, point lies on curve:
\[
y_0 = \frac{C}{x_0 + 1} \quad \text{(2)}
\]
Now since line is tangent to curve and also passes through both (0, 3) and (5, -2), every point on the curve and tangent must satisfy:
\[
y = -x + 3 \quad \text{(line equation from two points)}
\]
So set:
\[
\frac{C}{x + 1} = -x + 3
\Rightarrow C = (x + 1)(-x + 3) = -x^2 + 2x + 3
\]
Max value of C occurs at vertex \( x = -\frac{b}{2a} = -\frac{2}{-2} = 1 \)
At \( x = 1 \):
\[
C = -(1)^2 + 2(1) + 3 = -1 + 2 + 3 = \boxed{4}
\]