The limit: \[ \lim_{x \to 0} \frac{\sin \left( \pi \sin^2 x \right)}{x^2} \] is equal to:
We are given the following limit: \[ \lim_{x \to 0} \frac{\sin \left( \pi \sin^2 x \right)}{x^2}. \] We need to evaluate this limit as \( x \to 0 \).
Step 1: Use the approximation for small \( x \), which is \( \sin x \approx x \) when \( x \) is close to 0. Therefore, for small \( x \), we have: \[ \sin^2 x \approx x^2. \] Thus, \( \pi \sin^2 x \approx \pi x^2 \).
Step 2: Now, substitute \( \pi x^2 \) into the sine function: \[ \sin \left( \pi \sin^2 x \right) \approx \sin \left( \pi x^2 \right). \] For small \( x \), we can use the approximation \( \sin y \approx y \) when \( y \) is small. Therefore: \[ \sin \left( \pi x^2 \right) \approx \pi x^2. \] Step 3: Substituting this approximation into the original limit expression, we get: \[ \lim_{x \to 0} \frac{\sin \left( \pi x^2 \right)}{x^2} \approx \lim_{x \to 0} \frac{\pi x^2}{x^2} = \pi. \] Thus, the correct answer is option (E).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: