Question:

The IUPAC name of the following compound is:

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Always assign the lowest locant to the highest-priority functional group (–CN>–OH>–Br), and number accordingly around the benzene ring.
Updated On: May 20, 2025
  • 1-Bromo-2-hydroxybenzonitrile
  • 2-Bromo-3-cyanophenol
  • 2-Bromo-3-hydroxybenzonitrile
  • 3-Hydroxy-2-bromobenzonitrile
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The Correct Option is C

Solution and Explanation

To name the compound using IUPAC rules:
1. Identify the parent chain: Benzene ring with substituents.
2. Principal functional group: Nitrile (–CN), which has highest priority, so suffix will be benzonitrile.
3. Number the ring: Start from –CN as position 1, and number in such a way that the other substituents get the lowest locants.
Structure:
- Position 1: –CN (priority group)
- Position 2: –Br
- Position 3: –OH
Putting it together: \[ \text{2-Bromo-3-hydroxybenzonitrile} \]
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