The Wurtz reaction is a method used to couple two alkyl halides in the presence of sodium metal, forming alkanes. It works best with straight-chain alkyl groups. When branched alkyl groups are used, the reaction is less effective and often does not occur efficiently because the formation of a branched alkane requires more complex conditions.
In this case, the compound in Option (B) with 8 carbon atoms is more branched and cannot be effectively synthesized through the Wurtz reaction.
Thus, the correct answer is Option (B).