Question:

The hybrids of which group elements of the periodic table form electron precise hybrids?

Updated On: Apr 11, 2025
  • group 12

  • group 13

  • group 14

  • group 16

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The Correct Option is C

Solution and Explanation

To solve the problem, we need to identify which group of elements in the periodic table form electron precise hydrides.

1. Understanding Electron Precise Hydrides:
Electron precise hydrides are those in which all valence electrons are involved in normal 2-center-2-electron (2c–2e) bonds. There are no electron deficiencies or lone pair electrons on the central atom in such compounds.

2. Analyze Each Group:

  • Group 12: Elements like Zn, Cd, Hg form hydrides that are mostly ionic or metallic, not electron precise.
  • Group 13: Forms electron deficient hydrides, e.g., $B_2H_6$ (diborane), which have multi-center bonding — hence not electron precise.
  • Group 14: Carbon, silicon, etc., form hydrides like $CH_4$, $SiH_4$, etc., which are electron precise. All valence electrons are involved in standard covalent bonds.
  • Group 16: Forms hydrides like $H_2O$, $H_2S$, etc., where lone pairs are present on the central atom — hence not electron precise.

Final Answer:
The correct answer is Group 14, as their hydrides are electron precise.

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Concepts Used:

Chemical Bonding and Molecular Structure

Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.

Types of Chemical Bonds:

There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds. 

  • Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
  • Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding. 
  • Hydrogen Bonds -  It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
  • Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.

Factors Affecting Bond Enthalpy in Chemical Bonding:

  • Size of the Atom
  • Multiplicity of Bonds
  • Number of Lone Pair of Electrons Present
  • Bond Angle