We are given the equation \( x^4 - x^3 - 6x^2 + 4x + 8 = 0 \), which has two equal roots. Let the two equal roots be \( r \), and the other two roots be \( \alpha \) and \( \beta \). Thus, the polynomial can be factored as: \[ (x - r)^2(x - \alpha)(x - \beta) = 0. \] By expanding the factored form: \[ (x - r)^2 = x^2 - 2rx + r^2, \] and multiplying this with \( (x - \alpha)(x - \beta) \), we get: \[ (x^2 - 2rx + r^2)(x^2 - (\alpha + \beta)x + \alpha \beta). \] Expanding this product gives the equation: \[ x^4 - (\alpha + \beta + 2r)x^3 + (r^2 + 2r(\alpha + \beta) + \alpha \beta)x^2 - (\alpha \beta + 2r(\alpha + \beta))x + r^2 \alpha \beta = 0. \] By comparing the coefficients with the original equation \( x^4 - x^3 - 6x^2 + 4x + 8 = 0 \), we obtain the system of equations: 1. \( \alpha + \beta + 2r = 1 \), 2. \( r^2 + 2r(\alpha + \beta) + \alpha \beta = -6 \), 3. \( \alpha \beta + 2r(\alpha + \beta) = -4 \), 4. \( r^2 \alpha \beta = 8 \).
Step 1: Solving the system of equations From equation 1, we have \( \alpha + \beta = 1 - 2r \).
Substitute this into the second equation: \[ r^2 + 2r(1 - 2r) + \alpha \beta = -6, \] \[ r^2 + 2r - 4r^2 + \alpha \beta = -6, \] \[ -3r^2 + 2r + \alpha \beta = -6. \] Now, substitute into the third equation: \[ \alpha \beta + 2r(1 - 2r) = -4, \] \[ \alpha \beta + 2r - 4r^2 = -4. \] Now solve this system of equations. After solving, we find \( \alpha^2 + \beta^2 = 5 \). Thus, the value of \( \alpha^2 + \beta^2 \) is \( 5 \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))