\[ \psi_{3,2,-2}(r,\theta,\phi) = R_{3}(r) Y_{2,-2}(\theta,\phi) \] Here, \( Y_{2,-2}(\theta, \phi) \) is a spherical harmonic function which is dependent on the angular variables \( \theta \) and \( \phi \). The spherical harmonic can be written as: \[ Y_{l,m}(\theta, \phi) = N_{l,m} P_{l}^{m}(\cos\theta) e^{im\phi} \] where \( P_{l}^{m}(\cos\theta) \) are the associated Legendre polynomials, and \( N_{l,m} \) is a normalization constant. For the given function \( Y_{2,-2}(\theta, \phi) \), we have \( m = -2 \).
Step 1: Apply the operator to the eigenfunction
We are tasked with finding the eigenvalue of the operator \( \sin \left( a \frac{\partial}{\partial \theta} \right) \) acting on the eigenfunction \( \psi_{3,2,-2}(r,\theta,\phi) \). Since the operator involves the derivative with respect to \( \theta \), the action of the operator on the angular part of the wavefunction is of primary interest.
\[ \sin \left( a \frac{\partial}{\partial \theta} \right) Y_{2,-2}(\theta, \phi) \]
Step 2: Effect of the derivative operator
The derivative operator \( \frac{\partial}{\partial \theta} \) acting on the spherical harmonic \( Y_{l,m}(\theta, \phi) \) gives a factor of \( m \), the magnetic quantum number. Specifically, for \( Y_{2,-2}(\theta, \phi) \), we have \( m = -2 \).
\[ \frac{\partial}{\partial \theta} Y_{2,-2}(\theta, \phi) \sim -2 Y_{2,-2}(\theta, \phi) \]
Step 3: Apply the sine operator
Now we apply the sine operator. The sine operator is a simple function that will act on the result of the derivative. Thus, we get the following result:
\[ \sin \left( a \frac{\partial}{\partial \theta} \right) Y_{2,-2}(\theta, \phi) = -\sin(2a) Y_{2,-2}(\theta, \phi) \]
Conclusion: Eigenvalue of the operator
From the above result, we see that the operator \( \sin \left( a \frac{\partial}{\partial \theta} \right) \) acting on the eigenfunction \( \psi_{3,2,-2}(r,\theta,\phi) \) gives the eigenvalue \( -\sin(2a) \). Thus, the eigenvalue is:
\( -\sin(2a) \)
A hydrogen atom consists of an electron revolving in a circular orbit of radius r with certain velocity v around a proton located at the nucleus of the atom. The electrostatic force of attraction between the revolving electron and the proton provides the requisite centripetal force to keep it in the orbit. According to Bohr’s model, an electron can revolve only in certain stable orbits. The angular momentum of the electron in these orbits is some integral multiple of \(\frac{h}{2π}\), where h is the Planck’s constant.
Ion | Q4+ | Xb+ | Yc+ | Zd+ |
---|---|---|---|---|
Radius (pm) | 53 | 66 | 40 | 100 |
Q4+, Xb+, Yc+, Zd+ are respectively
In the following Venn diagram, which of the following represents the educated men but not urban?