\[ \psi_{3,2,-2}(r,\theta,\phi) = R_{3}(r) Y_{2,-2}(\theta,\phi) \] Here, \( Y_{2,-2}(\theta, \phi) \) is a spherical harmonic function which is dependent on the angular variables \( \theta \) and \( \phi \). The spherical harmonic can be written as: \[ Y_{l,m}(\theta, \phi) = N_{l,m} P_{l}^{m}(\cos\theta) e^{im\phi} \] where \( P_{l}^{m}(\cos\theta) \) are the associated Legendre polynomials, and \( N_{l,m} \) is a normalization constant. For the given function \( Y_{2,-2}(\theta, \phi) \), we have \( m = -2 \).
Step 1: Apply the operator to the eigenfunction
We are tasked with finding the eigenvalue of the operator \( \sin \left( a \frac{\partial}{\partial \theta} \right) \) acting on the eigenfunction \( \psi_{3,2,-2}(r,\theta,\phi) \). Since the operator involves the derivative with respect to \( \theta \), the action of the operator on the angular part of the wavefunction is of primary interest.
\[ \sin \left( a \frac{\partial}{\partial \theta} \right) Y_{2,-2}(\theta, \phi) \]
Step 2: Effect of the derivative operator
The derivative operator \( \frac{\partial}{\partial \theta} \) acting on the spherical harmonic \( Y_{l,m}(\theta, \phi) \) gives a factor of \( m \), the magnetic quantum number. Specifically, for \( Y_{2,-2}(\theta, \phi) \), we have \( m = -2 \).
\[ \frac{\partial}{\partial \theta} Y_{2,-2}(\theta, \phi) \sim -2 Y_{2,-2}(\theta, \phi) \]
Step 3: Apply the sine operator
Now we apply the sine operator. The sine operator is a simple function that will act on the result of the derivative. Thus, we get the following result:
\[ \sin \left( a \frac{\partial}{\partial \theta} \right) Y_{2,-2}(\theta, \phi) = -\sin(2a) Y_{2,-2}(\theta, \phi) \]
Conclusion: Eigenvalue of the operator
From the above result, we see that the operator \( \sin \left( a \frac{\partial}{\partial \theta} \right) \) acting on the eigenfunction \( \psi_{3,2,-2}(r,\theta,\phi) \) gives the eigenvalue \( -\sin(2a) \). Thus, the eigenvalue is:
\( -\sin(2a) \)
List I (Spectral Lines of Hydrogen for transitions from) | List II (Wavelength (nm)) | ||
A. | n2 = 3 to n1 = 2 | I. | 410.2 |
B. | n2 = 4 to n1 = 2 | II. | 434.1 |
C. | n2 = 5 to n1 = 2 | III. | 656.3 |
D. | n2 = 6 to n1 = 2 | IV. | 486.1 |
The angular momentum of an electron in a stationary state of \(Li^{2+}\) (\(Z=3\)) is \( \frac{3h}{\pi} \). The radius and energy of that stationary state are respectively.