Step 1: Understanding the Given Temperatures - The Celsius-Fahrenheit coincidence occurs at: \[ T_1 = -40^\circ C = 233 \text{ K}. \] - The Kelvin-Fahrenheit coincidence occurs at: \[ T_2 = 574.25 \text{ K}. \]
Step 2: Applying Carnot’s Efficiency Formula The efficiency of a Carnot engine is given by: \[ \eta = 1 - \frac{T_C}{T_H}. \] Substituting values: \[ \eta = 1 - \frac{233}{574.25}. \] \[ \eta = 1 - 0.4059. \] \[ \eta = 0.594 \approx 60%. \] Thus, the correct answer is: 60%.
Step 1: Identifying the Special Temperatures
We are given two specific temperature points that are notable due to their unique relationships across different temperature scales:
- The Celsius-Fahrenheit coincidence occurs at:
\( T_1 = -40^\circ C \)
To convert this to the Kelvin scale:
\( T(K) = T(°C) + 273.15 \)
\( T_1 = -40 + 273.15 = 233.15 \text{ K} \approx 233 \text{ K} \)
- The Kelvin-Fahrenheit coincidence point is given directly as:
\( T_2 = 574.25 \text{ K} \)
These values are used as the temperatures for the cold reservoir (\( T_C = 233 \text{ K} \)) and the hot reservoir (\( T_H = 574.25 \text{ K} \)) of a Carnot heat engine.
Step 2: Understanding the Carnot Engine Efficiency
The efficiency of a Carnot engine operating between two thermal reservoirs is given by the formula:
\( \eta = 1 - \frac{T_C}{T_H} \)
where:
- \( \eta \) is the efficiency (expressed as a decimal)
- \( T_C \) is the cold reservoir temperature in Kelvin
- \( T_H \) is the hot reservoir temperature in Kelvin
Step 3: Substituting the Values
Plugging in the known values:
\( \eta = 1 - \frac{233}{574.25} \)
\( \eta = 1 - 0.4059 \)
\( \eta = 0.5941 \)
Converting to a percentage:
\( \eta \times 100 = 59.41\% \)
Rounding to the nearest whole number:
\( \eta \approx 60\% \)
Final Answer:
The ideal efficiency of the Carnot engine under these conditions is approximately 60%.
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.