Step 1: Understanding Carnot Efficiency Formula The efficiency \( \eta \) of a Carnot engine is given by: \[ \eta = 1 - \frac{T_C}{T_H} \] where \( T_C \) is the sink (low-temperature reservoir) temperature, and \( T_H \) is the source (high-temperature reservoir) temperature.
Step 2: Setting Up Equations for Given Conditions We are given that initially: \[ \frac{1}{6} = 1 - \frac{T_C}{T_H} \] Rearranging, \[ \frac{T_C}{T_H} = 1 - \frac{1}{6} = \frac{5}{6} \] Thus, \[ T_C = \frac{5}{6} T_H \] After lowering the sink temperature by 65 K, the efficiency increases to \( \frac{1}{3} \), so: \[ \frac{1}{3} = 1 - \frac{T_C - 65}{T_H} \] \[ \frac{T_C - 65}{T_H} = 1 - \frac{1}{3} = \frac{2}{3} \] Thus, \[ T_C - 65 = \frac{2}{3} T_H \]
Step 3: Solving for \( T_H \) and \( T_C \) From the two equations: 1. \( T_C = \frac{5}{6} T_H \) 2. \( T_C - 65 = \frac{2}{3} T_H \) Substituting the first equation into the second: \[ \frac{5}{6} T_H - 65 = \frac{2}{3} T_H \] Multiplying everything by 6 to clear fractions: \[ 5 T_H - 390 = 4 T_H \] \[ T_H = 390 \text{ K} \] Now, substituting into \( T_C = \frac{5}{6} T_H \): \[ T_C = \frac{5}{6} \times 390 = 325 \text{ K} \] After decreasing by 65 K: \[ T_C' = 325 - 65 = 260 \text{ K} \] Thus, the initial and final sink temperatures are 325 K and 260 K, respectively.
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
A 3 kg block is connected as shown in the figure. Spring constants of two springs \( K_1 \) and \( K_2 \) are 50 Nm\(^{-1}\) and 150 Nm\(^{-1}\) respectively. The block is released from rest with the springs unstretched. The acceleration of the block in its lowest position is ( \( g = 10 \) ms\(^{-2}\) )