For polar molecules, the interaction energy between two dipoles is given by the formula: \[ U(r) = \frac{C}{r^6} \] where \( C \) is a constant and \( r \) is the distance between the molecules. This relationship arises due to the nature of dipole-dipole interactions, where the energy is inversely proportional to the sixth power of the distance between the dipoles.
Thus, the dipole-dipole interaction energy between rotating polar molecules is proportional to \( \frac{1}{r^6} \).
The correct option is (E) : \(\frac{1}{r^6}\)
Assertion (A): The boiling point of ethanol is higher than that of methoxymethane. Reason (R): There is intramolecular hydrogen bonding in ethanol.
Reaction \( 2A \rightarrow B + 3C \) is a zero-order reaction. What will be the rate of production for "C"?
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: