Question:

The de-Broglie wavelength associated with electron of hydrogen atom in this ground state is

Updated On: Apr 2, 2025
  • \(0.3 A˚\)

  • \(3.3  A˚\)

  • \(6.26  A˚\)

  • \(10 A˚\)

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The Correct Option is B

Approach Solution - 1

De-Broglie wavelength is given by
$\lambda=12.27 / \sqrt{ E }_{0}$,
where $E _{0}$ is the ground state energy of the hydrogen atom
whose value is $13.6\, V$
$\therefore \lambda=12.27 /(\sqrt{1} 3.6)=3.33 \,?$
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Approach Solution -2

The de-Broglie wavelength \( \lambda \) associated with an electron is given by the formula: \[ \lambda = \frac{h}{mv} \] Where: - \( h \) is Planck's constant (\( 6.626 \times 10^{-34} \, \text{J·s} \)), - \( m \) is the mass of the electron (\( 9.11 \times 10^{-31} \, \text{kg} \)), - \( v \) is the velocity of the electron. For a hydrogen atom in its ground state, the velocity of the electron is given by the Bohr model of the atom: \[ v = \frac{2 \pi k e^2}{h} \] Using the known values for constants and the radius of the electron's orbit in the ground state (\( r = 5.3 \times 10^{-11} \, \text{m} \)), we can calculate the wavelength of the electron. The result gives: \[ \lambda = 3.3 \, \text{Å} \] Thus, the de-Broglie wavelength associated with the electron in the ground state of the hydrogen atom is 3.3 Å.

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Concepts Used:

De Broglie Hypothesis

One of the equations that are commonly used to define the wave properties of matter is the de Broglie equation. Basically, it describes the wave nature of the electron.

De Broglie Equation Derivation and de Broglie Wavelength

Very low mass particles moving at a speed less than that of light behave like a particle and waves. De Broglie derived an expression relating to the mass of such smaller particles and their wavelength.

Plank’s quantum theory relates the energy of an electromagnetic wave to its wavelength or frequency.

E  = hν     …….(1)

E = mc2……..(2)

As the smaller particle exhibits dual nature, and energy being the same, de Broglie equated both these relations for the particle moving with velocity ‘v’ as,

This equation relating the momentum of a particle with its wavelength is de Broglie equation and the wavelength calculated using this relation is the de Broglie wavelength.