The extent of adsorption of a gas on activated charcoal increases with the critical temperature of the gas. The critical temperature is the temperature above which a gas cannot be liquefied, regardless of pressure. Gases with higher critical temperatures are more easily liquefied and are adsorbed to a greater extent.
Given the critical temperatures:
- Methane: 190K
- Ammonia: 405K
- Carbon dioxide: 304K
- n-Butane: 425K
- Dihydrogen: 33K
Among these, n-butane has the highest critical temperature (425K), which means it is the gas that will be adsorbed to the maximum extent on activated charcoal at a given temperature.
The correct option is (D) : n-butane
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: