Step 1: Understand metallic character and its periodic trends.
Metallic character refers to the tendency of an element to lose electrons and form positive ions. It generally:
Decreases from left to right across a period
Increases from top to bottom in a group
Is related to lower ionization energy and electronegativity
Step 2: Analyze the positions of the given elements in the periodic table.
Na (Sodium): Group 1, Period 3
Mg (Magnesium): Group 2, Period 3
Al (Aluminum): Group 13, Period 3
Si (Silicon): Group 14, Period 3
All these elements are in the same period (Period 3), so metallic character decreases as we move from left to right.
Step 3: Determine the correct order.
Since all elements are in the same period and metallic character decreases from left to right, the correct order of decreasing metallic character is:
Na>Mg>Al>Si
Final Answer:
\[
\boxed{\text{Na>Mg>Al>Si}}
\]