To determine the relative stability of the given conformers of n-butane, we analyze the Newman projections about the central C–C bond.
Conformer II: This is the anti-conformation where the two methyl groups (CH₃) are 180° apart. It is the most stable due to minimal steric hindrance.
Conformer I and III: Both are gauche conformations, where the methyl groups are 60° apart. These are less stable than anti due to gauche interactions (steric repulsion between bulky groups), but they are equally stable with respect to each other.
Hence, the correct order of relative stability is:
II > I = III
List-I | List-II | ||
(A) | 1 mol of H2O to O2 | (I) | 3F |
(B) | 1 mol of MnO-4 to Mn2+ | (II) | 2F |
(C) | 1.5 mol of Ca from molten CaCl2 | (III) | 1F |
(D) | 1 mol of FeO to Fe2O3 | (IV) | 5F |
Identify the products C, D, and F formed in the following sets of reactions.
Which one of the following is the correct order of reagents to be used to convert [A] to [X]?
A beam of light of wavelength \(\lambda\) falls on a metal having work function \(\phi\) placed in a magnetic field \(B\). The most energetic electrons, perpendicular to the field, are bent in circular arcs of radius \(R\). If the experiment is performed for different values of \(\lambda\), then the \(B^2 \, \text{vs} \, \frac{1}{\lambda}\) graph will look like (keeping all other quantities constant).