Question:

The CORRECT option(s) of ( Y ) for the following reaction is/are: 

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The ( ce{2,4-dinitrophenylhydrazine} ) test is used to detect aldehydes and ketones. Esters, amides, and other functional groups do not form hydrazones with ( ce{2,4-dinitrophenylhydrazine} ).
Updated On: Feb 2, 2025
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The Correct Option is A, C

Solution and Explanation

Step 1: Reaction mechanism overview.

This reaction involves the formation of a 2,4-dinitrophenylhydrazone derivative, a classic test for the presence of carbonyl compounds (aldehydes and ketones). The \( \ce{2,4-dinitrophenylhydrazine} \) reacts with carbonyl compounds to form hydrazones. The reaction is highly specific for compounds with a carbonyl group (\( \ce{-CHO} \) or \( \ce{C=O} \)).

Step 2: Analyzing the options.
  • Option (A): Contains a carbonyl group (\( \ce{-CHO} \)), making it reactive under the given conditions.
  • Option (B): Contains an ester functional group (\( \ce{COOR} \)), which does not react with \( \ce{2,4-dinitrophenylhydrazine} \).
  • Option (C): Contains a carbonyl group (\( \ce{C=O} \)), making it reactive under the given conditions.
  • Option (D): Contains an amide group (\( \ce{CONH2} \)), which does not react with \( \ce{2,4-dinitrophenylhydrazine} \).
Step 3: Conclusion.

The compounds with a reactive carbonyl group are present in options (A) and (C).

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