Step 1: Identify the substance. Gunpowder, also known as black powder, is the earliest known chemical explosive.
Step 2: Recall its composition. It consists of three main components:
Potassium nitrate (\(KNO_3\)): The oxidizer.
Charcoal (Carbon): The fuel.
Sulphur: A secondary fuel and stabilizer that lowers the ignition temperature.
Step 3: Check the proportions. The standard optimal composition for black powder is approximately 75% potassium nitrate, 15% charcoal, and 10% sulfur by weight. Option (1) lists proportions that are very close to this standard (with sulfur and charcoal percentages swapped, which is a common variation). Options (2) and (4) describe smokeless powders like cordite, not traditional gunpowder. Option (3) is an incorrect mixture.