Critical angle $C$ is given by $\sin C = \dfrac{1}{\mu}$, where $\mu$ is the refractive index.
Higher the wavelength of light, lower the refractive index, and hence higher the critical angle.
Among visible light, red light has the longest wavelength (≈700 nm) and thus the lowest refractive index.
Therefore, red has the highest critical angle of incidence.