The colour of $KMnO_4 $ is due to
- $M \rightarrow L $ charge transfer transition
- $\sigma \rightarrow \sigma $ transition
- $L \rightarrow M $ charge transfer transition
- $\sigma \rightarrow \sigma ^*$ transition
The Correct Option is C
Solution and Explanation
Top Questions on d block elements
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Questions Asked in JEE Main exam
- Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : If Young’s double slit experiment is performed in an optically denser medium than air, then the consecutive fringes come closer.
Reason (R) : The speed of light reduces in an optically denser medium than air while its frequency does not change.
In the light of the above statements, choose the most appropriate answer from the options given below : - The increase in pressure required to decrease the volume of a water sample by 0.2percentage is \( P \times 10^5 \, \text{Nm}^{-2} \). Bulk modulus of water is \( 2.15 \times 10^9 \, \text{Nm}^{-2} \). The value of \( P \) is ________________.
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The motion of an airplane is represented by the velocity-time graph as shown below. The distance covered by the airplane in the first 30.5 seconds is km.
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Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
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(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.
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Concepts Used:
d block elements
The elements, in the columns of the periodic table in which d subshells are being occupied are known as d block elements.
These are the elements that have the capability of forming stable cations with incompletely filled d orbitals. Elements like mercury and Zinc are not considered transition metals because they have electronic configurations: (n-1)d10 ns2. These elements have filled d-orbitals in their ground state and, therefore, even in some of their oxidation states.
General Properties Of d-Block Elements
- Multiple oxidation states- The oxidation states of d block elements show very few energy gaps; therefore, they exhibit many oxidation states. Also, the energy difference between s and d orbital is very less. Therefore both the electrons are involved in ionic and covalent bond formation, which ultimately leads to multiple oxidation states.
- Formation of complex compounds- Ligands show a binding behaviour and can form so many stable complexes with the help of transition metals. This property is mainly due to:
- Availability of vacant d orbitals.
- Comparatively small sizes of metals.
- Hardness- Transition elements are tough and have high densities because of the presence of unpaired electrons.
- Melting and boiling points- Melting and boiling points of transition are very high. This is because of the presence of unpaired electrons and partially filled d orbitals. Because of these two things, they form strong bonds and therefore have high melting and boiling points.
- Atomic radii- The atomic and ionic radius of the transition elements decreases as we move from Group 3 to group 6. However, it remains the same between group 7 and group 10, and from group 11 to group 12 increases.
- Ionization enthalpy- The ionization enthalpies of the transition elements are generally on the greater side as compared to the S block elements