Consider a process with transfer function: \[ G_p = \frac{2e^{-s}}{(5s + 1)^2} \] A first-order plus dead time (FOPDT) model is to be fitted to the unit step process reaction curve (PRC) by applying the maximum slope method. Let \( \tau_m \) and \( \theta_m \) denote the time constant and dead time, respectively, of the fitted FOPDT model. The value of \( \frac{\tau_m}{\theta_m} \) is __________ (rounded off to 2 decimal places).
Given: For \( G = \frac{1}{(\tau s + 1)^2} \), the unit step output response is: \[ y(t) = 1 - \left(1 + \frac{t}{\tau}\right)e^{-t/\tau} \] The first and second derivatives of \( y(t) \) are: \[ \frac{dy(t)}{dt} = \frac{t}{\tau^2} e^{-t/\tau} \] \[ \frac{d^2y(t)}{dt^2} = \frac{1}{\tau^2} \left(1 - \frac{t}{\tau}\right) e^{-t/\tau} \]
An ideal monoatomic gas is contained inside a cylinder-piston assembly connected to a Hookean spring as shown in the figure. The piston is frictionless and massless. The spring constant is 10 kN/m. At the initial equilibrium state (shown in the figure), the spring is unstretched. The gas is expanded reversibly by adding 362.5 J of heat. At the final equilibrium state, the piston presses against the stoppers. Neglecting the heat loss to the surroundings, the final equilibrium temperature of the gas is __________ K (rounded off to the nearest integer).
The residence-time distribution (RTD) function of a reactor (in min$^{-1}$) is 
The mean residence time of the reactor is __________ min (rounded off to 2 decimal places).}
Ideal nonreacting gases A and B are contained inside a perfectly insulated chamber, separated by a thin partition, as shown in the figure. The partition is removed, and the two gases mix till final equilibrium is reached. The change in total entropy for the process is _________J/K (rounded off to 1 decimal place).
Given: Universal gas constant \( R = 8.314 \) J/(mol K), \( T_A = T_B = 273 \) K, \( P_A = P_B = 1 \) atm, \( V_B = 22.4 \) L, \( V_A = 3V_B \).
The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:
\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is __________ MPa (rounded off to 3 decimal places).